Soil Chemistry & Plant Nutrition

Educational tool only

An interactive teaching tool — UC Davis Advanced Irrigation Lab

General / all-crop defaults

Nutrient Roles & Deficiency Symptoms

Deficiency chart of micronutrients illustrated on a plant stem
NutrientClassPrimary role(s)
Nitrogen (N)MacroAmino acids, proteins, chlorophyll, nucleic acids — drives vegetative growth
Phosphorus (P)MacroATP/energy transfer, root development, DNA/RNA, flowering & seed set
Potassium (K)MacroStomatal regulation, osmotic balance, enzyme activation, water-use efficiency
Calcium (Ca)Macro (secondary)Cell wall structure (middle lamella), membrane stability, signaling
Magnesium (Mg)Macro (secondary)Central atom of chlorophyll; enzyme cofactor for phosphorylation
Sulfur (S)Macro (secondary)Amino acids (cysteine, methionine), enzyme cofactors, oil synthesis
Iron (Fe)MicroChlorophyll synthesis, electron transport (cytochromes), N fixation enzymes
Manganese (Mn)MicroPhotosystem II water-splitting, enzyme activation, lignin synthesis
Zinc (Zn)MicroAuxin (growth hormone) synthesis, enzyme structure, internode elongation
Copper (Cu)MicroLignin synthesis, electron transport, pollen viability
Boron (B)MicroCell wall cross-linking, pollen tube growth, sugar transport
Molybdenum (Mo)MicroNitrate reductase & nitrogenase — essential for N metabolism/fixation
Chlorine (Cl)MicroOsmotic regulation, photosystem II, disease resistance in some crops
Nickel (Ni)MicroUrease enzyme cofactor — required for urea nitrogen metabolism

Mobility & Deficiency Symptom Location

Some nutrients can be resorbed from old tissue and shuttled to new growth when supply runs short (mobile); others, once deposited, stay put (immobile). This single property predicts where on the plant a deficiency symptom will first appear — a fast, practical diagnostic shortcut.

Select a nutrient above.
Mobile (old leaves first)Immobile (new growth first)
N, P, K, Mg, Mo, ClCa, S, Fe, Mn, Zn, Cu, B

S is a partial exception — technically somewhat mobile, but often behaves more like N in the field, so labs sometimes list it either way.

How Soil pH Controls Nutrient Availability

Soil pH doesn't add or remove nutrients directly — it changes their chemical form and solubility, which determines how much of each nutrient is actually dissolved in soil solution and accessible to roots. Drag the slider to see how the availability "window" shifts for each nutrient.

Slightly acidic — near-optimal for most nutrients
Select a pH value to see a summary.

Nutrient Availability at This pH

Relative availability (0–100%) for each nutrient at the pH selected above — updates live with the slider.

Why this happens

pH rangeMechanism
< 5.5 (strongly acidic)Al³⁺ and Mn²⁺ dissolve into toxic concentrations; P binds tightly to Fe/Al oxides; Ca, Mg, K, Mo become scarce or leach easily.
5.5 – 7.5 (near-neutral)Widest availability window — most macro- and micronutrients are in soluble, plant-usable forms simultaneously. This is why ~6.0–7.0 is the general target for most crops.
> 7.5 (alkaline / calcareous)Fe, Mn, Zn, Cu, and B precipitate as insoluble hydroxides/carbonates ("lime-induced chlorosis"); P re-precipitates with Ca; Mo availability actually increases.

Nitrogen Form & the Rhizosphere pH Feedback Loop

The form of N a root absorbs changes the local (rhizosphere) pH — which then feeds back into the micro-scale nutrient availability right at the root surface, on top of the bulk-soil pH effects shown above.

NH₄⁺ (ammonium) uptake

Roots take in a positive ion, so they release H⁺ to balance charge → rhizosphere acidifies. Common with ammonium-based or urea fertilizers, especially in cooler/wetter soils where nitrification is slow.

NO₃⁻ (nitrate) uptake

Roots take in a negative ion, so they release OH⁻/HCO₃⁻ to balance charge → rhizosphere alkalinizes. Common in warm, well-aerated, biologically active soils where nitrification runs fast.

Practical implication: on already-alkaline, high-pH soils (see above), favoring NH₄⁺/urea-based N sources can locally counteract micronutrient lockout at the root surface. On acidic soils prone to Al toxicity, NO₃⁻-based sources can help avoid further local acidification.

Soil Organic Matter, Carbon & C:N Ratio

Organic Carbon vs. Soil Organic Matter

Soil organic matter (SOM) is not pure carbon — it's a mix of carbon, hydrogen, oxygen, nitrogen and other elements bound into humus, roots, microbial biomass, and residues. Labs typically measure %OC (organic carbon) directly by combustion, then convert to %SOM using the van Bemmelen factor, since SOM is conventionally assumed to be ~58% carbon by weight (1 ÷ 0.58 ≈ 1.724).

Convert %OC ⇄ %SOM

0%1.50%8%
1.70 (older mineral-soil default)1.7242.00 (organic/peat soils)
Organic carbon
1.50%
→ Organic matter
2.59%

Why it matters agronomically

Each 1% increase in SOM in the top 15 cm roughly corresponds to:

  • ~1,000–1,200 liter ha⁻¹ additional water-holding capacity
  • A slow-release reservoir of N, P, and S mineralized by microbial activity
  • Better soil aggregation, infiltration, and resistance to compaction
Typical mineral agricultural soils: 1–6% SOM (0.6–3.5% OC). Peat/organic soils: >20% SOM.

Cation Exchange Capacity & Base Saturation

CEC is the soil's capacity to hold positively charged nutrients (Ca²⁺, Mg²⁺, K⁺, NH₄⁺) on negatively charged clay and organic matter surfaces — directly boosted by the organic matter discussed above — think of it as the soil's "nutrient bank account." Base saturation describes what fraction of that account is filled with base cations versus acidic H⁺/Al³⁺.

0%25%60%
0%2.5%8%
Estimated CEC
cmol(+)/kg

Rough estimate: clay ≈ 0.5–1.0 cmol/kg per %, montmorillonitic assumption; SOM ≈ 2 cmol/kg per % — illustrative only, texture/mineralogy vary widely.

4.06.58.5
Est. base saturation
Cation% of CECcmol(+)/kg
Ca²⁺
Mg²⁺
K⁺
H⁺/Al³⁺ (acidity)
Base saturation is estimated from pH using a general mineral-soil correlation, then split into Ca:Mg:K using typical agronomic proportions (~78:15:7). Actual values depend on soil mineralogy, base cation source, and buffering capacity — a lab base saturation test is the reliable measurement.

C:N Ratio & Decomposition

Soil microbes need roughly 24 units of carbon for every 1 unit of nitrogen to build their own biomass. If the residue they're decomposing has a much wider ratio than that, they scavenge mineral N from the soil (immobilization) — temporarily competing with your crop. A narrower ratio releases surplus N into the soil (mineralization), feeding plants.

Blend calculator

Set the relative mass proportions of two organic inputs to see the resulting blended C:N ratio.

Material
C:N ratio
Mass share

Shares are normalized automatically (they don't need to sum to 100).

Result

Blended C:N
10:1~24:1 (equilibrium)~30:1100:1+

Limiting Factors & Nutrient Interactions

Liebig's Law of the Minimum

Crop yield is capped by whichever essential nutrient is scarcest relative to demand — not by the average or sum of all nutrients supplied. Classically illustrated as a barrel: the shortest stave sets how much water (yield) the barrel can hold, no matter how tall the other staves are.

Adjust each nutrient's relative supply (0–100% of crop demand), or apply a crop's typical relative demand pattern below. The barrel fills only to the shortest stave.

Limiting nutrient
Effective yield potential
Raising any non-limiting nutrient does nothing for yield until the limiting one is addressed — a core reason balanced fertility programs outperform "more of everything" approaches.

Nutrient Interactions & Antagonism

Nutrients don't act in isolation — applying one in excess can physically or chemically block uptake of another, usually because they compete for the same root uptake transporters or exchange sites. Select a nutrient to see what it commonly antagonizes or synergizes with.

Select a nutrient above.

Deficiency Thresholds & Checker

Deficiency Threshold Reference Values

Deficiency is diagnosed against two kinds of measured numbers: a soil test critical level (below which a fertilizer response is expected) and a plant tissue sufficiency range (from lab analysis of a specific leaf position, usually the most recently matured leaf). Exact cutoffs vary by lab, extraction method, crop, and growth stage — the figures below are commonly cited general reference ranges for row/vegetable crops, not a substitute for a lab's own calibrated ranges.

NutrientSoil test methodSoil deficient belowSoil sufficient rangeTissue deficient belowTissue sufficient range
NNO₃-N, 0–30 cm10 ppm15–40 ppm2.0%2.5–4.0%
POlsen (bicarbonate)8 ppm15–30 ppm0.15%0.20–0.50%
KAmmonium acetate (exch.)60 ppm100–200 ppm1.0%1.5–3.0%
CaAmmonium acetate (exch.)400 ppm800–2000 ppm0.3%0.5–2.0%
MgAmmonium acetate (exch.)40 ppm60–150 ppm0.15%0.25–0.60%
SMonocalcium phosphate (SO₄-S)5 ppm8–20 ppm0.10%0.15–0.30%
FeDTPA2.0 ppm2.5–10 ppm40 ppm50–150 ppm
MnDTPA1.0 ppm1.5–10 ppm15 ppm20–100 ppm
ZnDTPA0.5 ppm0.8–2.5 ppm15 ppm20–50 ppm
CuDTPA0.2 ppm0.3–1.5 ppm4 ppm5–15 ppm
BHot-water extraction0.3 ppm0.5–2.0 ppm15 ppm20–60 ppm
MoAmmonium oxalate0.05 ppm0.1–0.3 ppm0.05 ppm0.1–1.0 ppm

Check a value

Pick a nutrient and test type, enter a measured value, and see how it classifies against the reference ranges above.

Classification

Typical Crop Nutrient Requirements

Total nutrient uptake for a mature crop, from planting to harvest — use the crop selector at the top of the page to highlight one crop's profile below the comparison table. Values are illustrative order-of-magnitude figures for teaching, not a fertilizer recommendation — actual removal depends heavily on yield, cultivar, and region.

CropNP₂O₅K₂OSCaMgYield basis

All values kg/ha total uptake (nutrient removed in harvested biomass + residue).

Select a crop from the dropdown at the top of the page to see its individual nutrient-uptake profile and peak-demand timing highlighted here.

Lab Report Analyzer & Recommendations

Enter values from a soil test or plant tissue analysis report and the tool will classify each nutrient against the reference ranges from the Deficiency Thresholds tab and generate general management recommendations. Leave any field blank if it wasn't measured. Select a crop from the dropdown at the top of the page first for crop-specific pH context.

These are general, principle-level teaching recommendations based on published reference ranges — not a substitute for a certified nutrient management plan, which should account for yield goals, irrigation water quality, prior fertilization, and local regulations.

Enter measured values

Classification

NutrientValueStatus

Recommendations